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Corrigendum to “Chemotaxonomic investigation of Apocynaceae for retronecine-type pyrrolizidine alkaloids using HPLC-MS/MS” [Phytochemistry 185 (2021) 112662]
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Corrigendum to “Chemotaxonomic investigation of Apocynaceae for retronecine-type pyrrolizidine alkaloids using HPLC-MS/MS” [Phytochemistry 185 (2021) 112662]

Lea A. Barny, Julia A. Tasca, Hugo A. Sanchez, Chelsea R. Smith, Suzanne Koptur, Tatyana Livshultz and Kevin P.C. Minbiole
Phytochemistry (Oxford), v 202, 113309
Oct 2022
url
https://doi.org/10.1016/j.phytochem.2022.113309View
Published, Version of Record (VoR) Open Maybe Open Access (Publisher Bronze)

Abstract

In this publication, using three precursor (PREC) analyses (low resolution LC-MS/MS), we suggested with low confidence that two compounds, yielding ions of m/z 432 and 328 Da, could be retronecine-type pyrrolizidine alkaloids (PAs). The compound exhibiting a mass of m/z 432 Da (herein referred to as compound 1) was detected in leaf samples of multiple Wrightia R.Br. species, Marsdenia tinctoria R.Br., M. glabra Costantin, as well as Wrightia tinctoria (Roxb.) R.Br. seeds. The compound exhibiting a mass of 328 Da (herein referred to as compound 2) was found in W. tinctoria seeds. We tentatively suggested that compound 1 could be 2-aminobenzoyl-O-β-D-apiofuranosyl-(1 → 6)- β- D-glucopyranoside (2-aminobenzoyl glycoside (Fig 1) and compound 2 blepharin (Fig 2), based on previous reports of specialized metabolites from Wrightia antidysenterica (L.) R.Br. and Wrightia religiosa (Teijsm. & Binn.) Benth. ex Kurz (Sahakitpichan et al., 2018; Srinroch et al., 2019; Traxler et al., 2021) and predicted fragmentation patterns. [1st paragraph]

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Collaboration types
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Biochemistry & Molecular Biology
Plant Sciences
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