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Additive-Free MXene Inks and Direct Printing of Micro-Supercapacitors
Book chapter   Open access

Additive-Free MXene Inks and Direct Printing of Micro-Supercapacitors

Chuanfang (John) Zhang, Lorcan McKeon, Matthias P. Kremer, Sang-Hoon Park, Oskar Ronan, Andrés Seral-Ascaso, Sebastian Barwich, Cormac Ó Coileáin, Niall McEvoy, Hannah C. Nerl, …
MXenes, pp 463-485
2023
url
https://www.osti.gov/biblio/1613000View

Abstract

Direct printing of functional inks is critical for applications in diverse areas including electrochemical energy storage, smart electronics and healthcare. However, the available printable ink formulations are far from ideal. Either surfactants/additives are typically involved or the ink concentration is low, which add complexity to the manufacturing and compromises the printing resolution. Here, we demonstrate two types of two-dimensional titanium carbide (Ti3C2T x ) MXene inks, aqueous and organic in the absence of any additive or binary-solvent systems, for extrusion printing and inkjet printing, respectively. We show examples of all-MXene-printed structures, such as microsupercapacitors, conductive tracks and ohmic resistors on untreated plastic and paper substrates, with high printing resolution and spatial uniformity. The volumetric capacitance and energy density of the all-MXene-printed micro-supercapacitors are orders of magnitude greater than existing inkjet/extrusionprinted active materials. The versatile direct-ink-printing technique highlights the promise of additive-free MXene inks for scalable fabrication of easy-to-integrate components of printable electronics.

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