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Development of surface-enhanced Raman scattering (SERS) substrates using nanoparticle-based printing inks
Conference proceeding

Development of surface-enhanced Raman scattering (SERS) substrates using nanoparticle-based printing inks

Manuel A. Figueroa, Sam Park, Kambiz Pourrezaei and Somdev Tyagi
COLLOIDAL QUANTUM DOTS FOR BIOMEDICAL APPLICATIONS III, v 6866(1), pp 686610-686616
01 Jan 2008

Abstract

Engineering Engineering, Biomedical Optics Physical Sciences Science & Technology Technology
Raman spectroscopy is now a well-established analytical tool for obtaining rapid and compound specific information for chemical analysis. However, Raman scattering - inelastic scattering of photons - cross sections are typically of the order of 10(-30) cm(2) per molecule and thus Raman signals are usually weak. In Surface Enhanced Raman Scattering (SERS) the signals can be greatly amplified by using specially structured metallic (usually Ag, Au, and Cu) substrates. SERS substrates can be fabricated by a variety of methods. Here, we report a method for fabricating SERS substrates from commercially available silver nanoparticle based printing inks. For dilute inks (similar to 1-2% Ag by weight) the method involves the airbrushing of inks on heated (similar to 100 degrees C) quartz or polymer substrates followed by heating at 170 degrees C for about 20 minutes. The heating treatment removes the polymer coating used to prevent aggregation of Ag particles in the colloidal suspension and allows partial sintering of particles. More concentrated inks (similar to 20 - 30% Ag by weight) can be applied to various substrates at room temperature followed by the thermal treatment. SERS spectra of Rhodamine 6G, and beta-carotene molecules are reported. SERS amplification factors of more than 10(6) can be easily obtained reproducibly.

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Web of Science research areas
Engineering, Biomedical
Optics
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