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Reducing Damage Due to Chemical Reactions in Concrete Exposed to Sodium Chloride: Quantification of a Deleterious Chemical Phase Change Formation
Conference proceeding   Open access   Peer reviewed

Reducing Damage Due to Chemical Reactions in Concrete Exposed to Sodium Chloride: Quantification of a Deleterious Chemical Phase Change Formation

Fadi Althoey and Yaghoob Farnam
MATEC Web of Conferences, v 271, p7004
01 Jan 2019
url
https://doi.org/10.1051/matecconf/201927107004View
Published, Version of Record (VoR) Open

Abstract

Calcium aluminate Chemical damage Chemical reactions Concrete deterioration Concrete pavements Dilution Fly ash Hydrates Organic chemistry Pastes Pavement deterioration Phase change Phase transitions Portland cements Silica fume Silicon dioxide Sodium chloride Thermal cycling Thermal energy Tricalcium aluminate Tricalcium aluminum ferrite
It has been shown that sodium chloride can react with the tricalcium aluminate (C3A) and its hydrates, leading to a formation of a deleterious chemical phase change during thermal cycling. It is believed that this chemical phase change is implicated in the premature deterioration of concrete pavements in the cold regions. This work examines the potential formation of the deleterious chemical phase change in several cementitious pastes made using different types of portland cement and supplementary cementitious materials (SCMs). The amount of the chemical phase change was quantified using a low-temperature differential scanning calorimetry. The results indicated that the formation of the chemical phase change can be reduced by using cements with low C3A content. The addition of SCMs showed different effects on the chemical phase change formation. Slag and Class F fly ash could reduce the amount of the chemical phase change due to only the dilution effect whereas silica fume could significantly reduce the amount of the chemical phase change due to the dilution effect as well as pozzolanic reactions. Adversely, the addition of Class C fly ash showed a negative effect through increasing the formation of the chemical phase change.

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