Journal article
3-D Microstructure Analysis of Fuel Cell Materials: Spatial Distributions of Tortuosity, Void Size and Diffusivity
Journal of the Electrochemical Society, v 159(3), pp B299-B307
01 Jan 2012
Featured in Collection : UN Sustainable Development Goals @ Drexel
Abstract
Due to the minute length scales and heterogeneous nature of fuel cell components, experimental quantification of the key properties of these materials can be expensive and quite difficult to conduct, if not impossible. The objective of this work is to introduce 3-D microstructure analysis tools for "direct" quantification of the key structure-related transport measures of porous fuel cell materials. Two important microstructure analysis tools are presented for the evaluation of tortuosity and void (i.e., pore) size distribution. The first tool is aimed at quantification of the tortuosity distribution in an internal structure using a shortest path search method. The second tool is aimed at quantification of orientation-resolved chord length distributions of a phase (e.g., void, solid) in a given 3-D microstructure dataset to extract the orientation and size related statistics of a selected phase. Various other key structure metrics (e.g, phase-specific volume fraction, phase connectivity, internal surface area etc.) are also successfully extracted by using these tools. Additionally, a 3-D diffusion model is presented to determine the effective structural diffusivity coefficient based on the measured microstructure. For demonstration purposes, these methods are applied to the measured microstructure datasets of the micro-porous layer of a polymer electrolyte fuel cell. (C) 2012 The Electrochemical Society. [DOI: 10.1149/2.068203jes] All rights reserved.
Metrics
Details
- Title
- 3-D Microstructure Analysis of Fuel Cell Materials: Spatial Distributions of Tortuosity, Void Size and Diffusivity
- Creators
- A. Cecen - Drexel UniversityE. A. Wargo - Drexel UniversityA. C. Hanna - Drexel UniversityD. M. Turner - Drexel UniversityS. R. Kalidindi - Drexel UniversityE. C. Kumbur - Drexel University
- Publication Details
- Journal of the Electrochemical Society, v 159(3), pp B299-B307
- Publisher
- Electrochemical Soc Inc
- Number of pages
- 9
- Grant note
- P200A100145 / U.S. Department of Education; US Department of Education 1066623; DMR-0722845 / National Science Foundation; National Science Foundation (NSF)
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- Mechanical Engineering and Mechanics
- Web of Science ID
- WOS:000299292100031
- Scopus ID
- 2-s2.0-84857419571
- Other Identifier
- 991019168153104721
UN Sustainable Development Goals (SDGs)
This publication has contributed to the advancement of the following goals:
InCites Highlights
Data related to this publication, from InCites Benchmarking & Analytics tool:
- Web of Science research areas
- Electrochemistry
- Materials Science, Coatings & Films