Journal article
A tetranuclear copper(II) complex with bis(o-aminobenzaldehyde)thiocarbohydrazone
INORGANICA CHIMICA ACTA, v 363(10), pp 2065-2070
20 Jun 2010
Featured in Collection : UN Sustainable Development Goals @ Drexel
Abstract
Bis(o-aminobenzaldehyde) thiocarbohydrazone (HL) forms with copper(II) nitrate a tetranuclear complex [Cu(2)(L)(NO(3))(3)](2)center dot 2H(2)O, in which two dinuclear units are joined by nitrate bridges. The dihydrazone ligand behaves ditopically, providing NNS and NNN binding sites, with the four coppers essentially in a square-pyramidal geometry. The tetranuclear molecule displays intramolecular magnetic interactions, with the antiferromagnetic exchange (-2J = 210(1) cm(-1)) between the copper(II) ions within each dinuclear moiety dominant over weak interdimer ferromagnetic coupling. (C) 2010 Elsevier B.V. All rights reserved.
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Details
- Title
- A tetranuclear copper(II) complex with bis(o-aminobenzaldehyde)thiocarbohydrazone
- Creators
- Diana Dragancea - Academy of Sciences of MoldovaAnthony W. Addison - Drexel UniversityMatthias Zeller - Youngstown State UniversityMichael E. Foster - Drexel UniversityMichael J. Prushan - Chemistry Department, LaSalle University, Philadelphia, PA 19141-1108, USALaurence K. Thompson - Memorial University of NewfoundlandMihail D. Revenco - Academy of Sciences of MoldovaAllen D. Hunter - Youngstown State University
- Publication Details
- INORGANICA CHIMICA ACTA, v 363(10), pp 2065-2070
- Publisher
- Elsevier
- Number of pages
- 6
- Grant note
- 09.836.05.02A / Supreme Council for Science and Technological Development Drexel University MTFP-022/05 / MRDA/CRDF foundation
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- Chemistry
- Web of Science ID
- WOS:000278592200002
- Scopus ID
- 2-s2.0-77954244067
- Other Identifier
- 991019168340704721
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- Collaboration types
- Domestic collaboration
- International collaboration
- Web of Science research areas
- Chemistry, Inorganic & Nuclear