Journal article
An Experimental Study of Propene Oxidation at Low and intermediate Temperatures
Combustion science and technology, v 52(1-3), pp 39-58
01 Mar 1987
Abstract
The oxidation of propene at low and intermediate temperatures (580-715 K) has been studied experimentally using a static reactor. Gas chromatographic analysis was used for stable species determination. The experimental results were used to postulate the main reaction paths of the mechanism. A region of negative temperature coefficient (NTC) was determined between 625-655 K and cool flames were indicated at temperatures below this range. Changes in the product distribution indicated that a transition in the mechanism was occurring across the region of NTC, from low to intermediate temperatures. The change in the mechanism with increasing temperature was attributed in part to the change in the position of equilibrium of CH
3
+ O
2
= CH
3
O
2
, and also to the competition between radical addition to the propene and H abstraction from the propene.
Metrics
Details
- Title
- An Experimental Study of Propene Oxidation at Low and intermediate Temperatures
- Creators
- R. D. Wilk - Department of Mechanical Engineering and Mechanics , Drexel UniversityN. P. Cernansky - Drexel UniversityR. S. Cohen - Department of Mechanical Engineering , Temple University
- Publication Details
- Combustion science and technology, v 52(1-3), pp 39-58
- Publisher
- Taylor & Francis Group
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- [Retired Faculty]
- Web of Science ID
- WOS:A1987H045200004
- Scopus ID
- 2-s2.0-0001917695
- Other Identifier
- 991019222531704721
InCites Highlights
Data related to this publication, from InCites Benchmarking & Analytics tool:
- Collaboration types
- Domestic collaboration
- Web of Science research areas
- Energy & Fuels
- Engineering, Chemical
- Engineering, Multidisciplinary
- Thermodynamics