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Anisotropic charge density wave in layered 1T-TiSe2
Journal article   Open access   Peer reviewed

Anisotropic charge density wave in layered 1T-TiSe2

Qiao Qiao, Songsong Zhou, Jing Tao, Jin-Cheng Zheng, Lijun Wu, Samuel T. Ciocys, Maria Iavarone, David J. Srolovitz, Goran Karapetrov and Yimei Zhu
Physical review materials, v 1(5)
04 Oct 2017
url
https://doi.org/10.1103/physrevmaterials.1.054002View
Accepted (AM)Open Access (Publisher-Specific) Open

Abstract

Materials Science Materials Science, Multidisciplinary Science & Technology Technology
We present a three-dimensional study on the anisotropy of the charge density wave (CDW) in 1T-TiSe2, by means of in situ atomically resolved electron microscopy at cryogenic temperatures in both reciprocal and real spaces. Using coherent nanoelectron diffraction, we observed short-range coherence of the in-plane CDW component while the long-range coherence of out-of-plane CDW component remains intact. An in-plane CDW coherence length of similar to 10 nm and an out-of-plane CDW coherence length of 17.5 nm, as a lower bound, were determined. The electron modulation was observed using electron energy-loss spectroscopy and verified by an orbital-projected density of states. Our integrated approach reveals anisotropic CDW domains at the nanoscale, and illustrates electron modulation-induced symmetry breaking of a two-dimensional material in three dimensions, offering an opportunity to study the effect of reduced dimensionality in strongly correlated systems.

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Materials Science, Multidisciplinary
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