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Accepted (AM)Open Access (License Unspecified), Open
Journal article
Asmic: An Exceptional Building Block for Isocyanide Alkylations
Organic letters, v 20(18), pp 5910-5913
21 Sep 2018
PMID: 30188137
Featured in Collection : UN Sustainable Development Goals @ Drexel
Abstract
Asmic addresses the long-standing challenge of alkylating isocyanides, providing access to isocyanides with diverse substitution patterns. The o-anisylsulfanyl group serves a critical dual role by facilitating deprotonation-alkylation and providing a latent nucleophilic site through an unusual arylsulfanyl-lithium exchange.
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Details
- Title
- Asmic: An Exceptional Building Block for Isocyanide Alkylations
- Creators
- Embarek Alwedi - Drexel UniversityJ. Armando Lujan-Montelongo - Drexel Univ, Dept Chem, 32 South 32nd St, Philadelphia, PA 19104 USABhaskar R. Pitta - Drexel UniversityAllen Chao - Drexel UniversityRodrigo Cortes-Mejia - Drexel UniversityJorge M. del Campo - Drexel UniversityFraser F. Fleming - Drexel University
- Publication Details
- Organic letters, v 20(18), pp 5910-5913
- Publisher
- American Chemical Society; Washington, DC
- Number of pages
- 4
- Grant note
- 2R15A1051352-04 / NIH; United States Department of Health & Human Services; National Institutes of Health (NIH) - USA 282791 / CONACYT; Consejo Nacional de Ciencia y Tecnologia (CONACyT) IN 114418 / DGAPA-UNAM; Universidad Nacional Autonoma de Mexico R15AI051352 / NATIONAL INSTITUTE OF ALLERGY AND INFECTIOUS DISEASES; United States Department of Health & Human Services; National Institutes of Health (NIH) - USA; NIH National Institute of Allergy & Infectious Diseases (NIAID) Drexel University
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- Chemistry
- Web of Science ID
- WOS:000445711500085
- Scopus ID
- 2-s2.0-85053295377
- Other Identifier
- 991019168491904721
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- Collaboration types
- Industry collaboration
- Domestic collaboration
- International collaboration
- Web of Science research areas
- Chemistry, Organic