Journal article
Asymmetric synthesis of the ab-ring of aklavinone
Tetrahedron letters, v 32(52), pp 7671-7674
1991
Featured in Collection : UN Sustainable Development Goals @ Drexel
Abstract
A formal synthesis of the AB-ring of aklavinone
3 was achieved via the asymmetric synthesis of diol
8 prepared in three steps from tetralone
5. The crucial step involved the asymmetric hydroxylation of
5 in ≥ 95% ee using (camphorylsulfonyl)oxaziridine derivative (+)-
4b.
A formal synthesis of the AB-ring of aklavinove
3 was achieved via the asymmetric synthesis of diol
8. The crucial step involved the asymmetric hydroxylation of the tetralone lithium enolate in ≥ 95% ee using (camphorylsulfonyl)oxaziridine derivative (+)-
4b.
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Details
- Title
- Asymmetric synthesis of the ab-ring of aklavinone
- Creators
- Franklin A. Davis - Drexel UniversityAnil Kumar - Drexel University
- Publication Details
- Tetrahedron letters, v 32(52), pp 7671-7674
- Publisher
- Elsevier
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- [Retired Faculty]
- Web of Science ID
- WOS:A1991GX96200011
- Scopus ID
- 2-s2.0-0026344177
- Other Identifier
- 991019173828004721
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- Web of Science research areas
- Chemistry, Organic