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Automated Scalpel Patterning of Solution Processed Thin Films for Fabrication of Transparent MXene Microsupercapacitors
Journal article   Peer reviewed

Automated Scalpel Patterning of Solution Processed Thin Films for Fabrication of Transparent MXene Microsupercapacitors

Pol Salles, Evan Quain, Narendra Kurra, Asia Sarycheva and Yury Gogotsi
Small (Weinheim an der Bergstrasse, Germany), v 14(44), pp e1802864-n/a
02 Nov 2018
PMID: 30286277

Abstract

microsupercapacitors dip‐coating transparent devices MXenes 2D materials
A simple and generic strategy is proposed to pattern thin films deposited by a solution processable route. A soft approach based on an automated scalpel technique is developed to engrave thin films in a single step for sculpting functional planar devices. MXenes—the emerging family of 2D transition metal carbides and nitrides—combine metallic conductivity and hydrophilicity, enabling solution processing of transparent conducting electrodes (TCEs) under ambient conditions. Scalable dip coating is employed to process titanium carbide, Ti3C2, MXene thin films with excellent optoelectronic properties, achieving electrical Figure of merit up to 14. Automated scalpel engraving is adopted to fabricate transparent and semi‐transparent MXene microsupercapacitors in a single step, hitherto not reported. Combining TCE and pseudocapacitive characteristics, MXene devices show excellent capacitive storage capabilities at high rates, without the aid of external metal current collectors. This technique allows for maskless patterning of solution processed thin films without losing intrinsic physicochemical properties and can be extended to fabricate heterostructured hybrid devices out of solution processable materials. Coplanar microdevices are fabricated by scraping patterns on MXene thin films directly using an automated scalpel technique.

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Web of Science research areas
Chemistry, Multidisciplinary
Chemistry, Physical
Materials Science, Multidisciplinary
Nanoscience & Nanotechnology
Physics, Applied
Physics, Condensed Matter
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