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Beyond Gold: Spin‐Coated Ti3C2‐Based MXene Photodetectors
Journal article   Peer reviewed

Beyond Gold: Spin‐Coated Ti3C2‐Based MXene Photodetectors

Kiana Montazeri, Marc Currie, Louisiane Verger, Pouya Dianat, Michel Barsoum and Bahram Nabet
Advanced materials (Weinheim), v 31(43), pp 1903271-n/a
12 Sep 2019
PMID: 31523860

Abstract

Chemical Sciences Material chemistry
2D transition metal carbides, known as MXenes, are transparent when the samples are thin enough. They are also excellent electrical conductors with metal-like carrier concentrations. Herein, these characteristics are exploited to replace gold (Au) in GaAs photodetectors. By simply spin-coating transparent Ti3C2-based MXene electrodes from aqueous suspensions onto GaAs patterned with a photoresist and lifted off with acetone, photodetectors that outperform more standard Au electrodes are fabricated. Both the Au- and MXene-based devices show rectifying contacts with comparable Schottky barrier heights and internal electric fields. The latter, however, exhibit significantly higher responsivities and quantum efficiencies, with similar dark currents, hence showing better dynamic range and detectivity, and similar sub-nanosecond response speeds compared to the Au-based devices. The simple fabrication process is readily integratable into microelectronic, photonic-integrated circuits and silicon photonics processes, with a wide range of applications from optical sensing to light detection and ranging and telecommunications.

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Collaboration types
Domestic collaboration
Web of Science research areas
Chemistry, Multidisciplinary
Chemistry, Physical
Materials Science, Multidisciplinary
Nanoscience & Nanotechnology
Physics, Applied
Physics, Condensed Matter
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