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Journal article
Bis[3-(anthracen-9-yl)pentane-2,4-dionato-kappa O-2,O ']-(N,N-dimethylformamiae-kappa O)[tris(pyrazol-1-yl-kappa N-2)hyaroborato]europium(III)
Acta crystallographica. Section E, Crystallographic communications, v 78(Pt 2), pp 103-107
01 Feb 2022
PMID: 35145732
Featured in Collection : UN Sustainable Development Goals @ Drexel
Abstract
The title compound, [Eu(C9H10BN6)(C19H15O2)(2)(C3H7NO)] or [TpEu(Anthracac)(2)(DMF)], was synthesized by reaction of a tris(pyrazolyl)borate (Tp(-)) Eu3+ complex with 3-(anthracen-9-yl)pentane-2,4-dione (HAnthracac) in the presence of triethylamine. In the title compound, Eu3+ is located in an octavertex square-pyramidal coordination environment. In the two Anthracac ligands, the anthracene and nearly planar acetylacetonate fragments are almost orthogonal. Neighboring molecules of TpEu(Anthracac)(2)(DMF) are connected in the crystal by intermolecular van der Waals interactions, while pi-stacking interactions are limited to the edges of two anthracene rings.
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Details
- Title
- Bis[3-(anthracen-9-yl)pentane-2,4-dionato-kappa O-2,O ']-(N,N-dimethylformamiae-kappa O)[tris(pyrazol-1-yl-kappa N-2)hyaroborato]europium(III)
- Creators
- Elena A. Mikhalyova - L.V. Pisarzhevskii Institute of Physical ChemistryMatthias Zeller - Purdue University West LafayetteJerry P. Jasinski - Keene State CollegeManpreet Kaur - Keene State CollegeAnthony W. Addison - Drexel University
- Publication Details
- Acta crystallographica. Section E, Crystallographic communications, v 78(Pt 2), pp 103-107
- Publisher
- Int Union Crystallography
- Number of pages
- 14
- Grant note
- 2020.02/0202 / National Research Foundation of Ukraine 32/20-N; 32/21-N / Target Program of Fundamental Research `Prospective fundamental studies and innovative developments of nanomaterials and nanotechnologies for the needs of industry, health protection and agriculture', National Academy of Sciences of Ukraine CHE-1039027 / NSF-MRI program; National Science Foundation (NSF); NSF - Office of the Director (OD)
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- Chemistry
- Web of Science ID
- WOS:000752907800002
- Scopus ID
- 2-s2.0-85124736863
- Other Identifier
- 991019168845304721
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- Collaboration types
- Domestic collaboration
- International collaboration
- Web of Science research areas
- Crystallography