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Cerebroside analogues from 3-phenylserines
Journal article   Peer reviewed

Cerebroside analogues from 3-phenylserines

Benjamin Weiss
Chemistry and physics of lipids, v 19(4), pp 347-355
Aug 1977
PMID: 908106

Abstract

Cerebroside analogues were synthesized from DL- threo-and DL- erythro-3-phenylserines by the following sequence of reactions: estirification, N-acylation, reduction with sodium bis (2-methoxyethoxy)-aluminum hydride (SMEAH), and condensation with acetobromoglucose followed by deacetylation. Mass spectrometry disclosed that the glycosidic bond was formed at the primary hydroxyl group.

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