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Characterization of highly conducting, ultra-thin polyaniline films produced by evaporative deposition
Journal article   Open access   Peer reviewed

Characterization of highly conducting, ultra-thin polyaniline films produced by evaporative deposition

R.V. Plank, Y. Wei, N.J. DiNardo and J.M. Vohs
Chemical physics letters, v 263(1)
1996
url
https://doi.org/10.1016/s0009-2614(96)01171-2View
Published, Version of Record (VoR)CC BY-NC-ND V4.0 Open
url
https://doi.org/10.1016/S0009-2614(96)01171-2View
Published, Version of Record (VoR) Open

Abstract

The chemical and electronic properties of ultra-thin polyaniline films produced by the evaporative deposition of emeraldine was studied using high resolution electron energy loss spectroscopy (HREELS). Vapor-deposited polyaniline films were found to consist of relatively short chains and exist in an oxidation state close to that of the starting emeraldine powder. Films doped with HCl exhibited a plasma frequency in the far-IR at low temperature. This indicates that ultra-thin, vapor-deposited emeraldine films are highly crystalline and, when doped with HCl, exhibit conductivities several orders of magnitude higher than those of HCl-doped emeraldine films produced by wet-chemical deposition techniques. The results of this study suggest that evaporative deposition may be an attractive fabrication technique for the production of polyaniline thin films for future applications in microelectronics.

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Collaboration types
Domestic collaboration
Web of Science research areas
Chemistry, Physical
Physics, Atomic, Molecular & Chemical
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