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Conformation of protonated trans- N-benzylideneaniline: a revisit
Journal article

Conformation of protonated trans- N-benzylideneaniline: a revisit

Hanying Xu, Karl Sohlberg and Yen Wei
Journal of molecular structure. Theochem, v 634(1), pp 311-314
2003

Abstract

Imine Schiff base π-Conjugation
The change in the degree of planarity of trans-N-benzylideneaniline upon protonation of the imine nitrogen is investigated with density functional theory caculations. Previous experimental work with nuclear magnetic resonance has suggested that the protonated species is more nearly planar, but theoretical work has suggested that protonation has no appreciable impact upon the planarity. The current calculations support the experimental results.

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Web of Science research areas
Chemistry, Physical
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