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Control of oleylamine to perovskite ratio in synthesis of MAPbBr(3) nanoparticles
Journal article   Peer reviewed

Control of oleylamine to perovskite ratio in synthesis of MAPbBr(3) nanoparticles

Jing Huang, Yi-Hua Wu, Zhi-Gang Zhu, Wan Y. Shih and Wei-Heng Shih
Chemical physics letters, v 702, pp 21-25
16 Jun 2018

Abstract

Chemistry Chemistry, Physical Physical Sciences Physics Physics, Atomic, Molecular & Chemical Science & Technology
Methylammonium lead bromide (CH3NH3PbBr3) nanocrystals have great potentials for lighting and display applications. Previously we synthesized CH3NH3PbBr3 nanocrystals using oleylamine as capping molecule and found that by increasing the oleylamine to CH3NH3PbBr3 perovskite ratio (OPR), the photoluminescence wavelengths and morphology of CH3NH3PbBr3 nanocrystals could be varied from 530 nm (green) platelets to 460 nm (blue) particles. Here we modified the synthesis to direct injection of precursors into toluene and found that increasing OPR not only changes the wavelength and morphology of nanocrystals but also the size of the unit cells. (C) 2018 Elsevier B.V. All rights reserved.

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Chemistry, Physical
Physics, Atomic, Molecular & Chemical
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