Journal article
Conversion constants for redox potentials measured versus different reference electrodes in acetonitrile solutions at 25°C
Inorganica Chimica Acta, v 298(1)
2000
Featured in Collection : UN Sustainable Development Goals @ Drexel
Abstract
Caution should be exercised when one is comparing the redox potentials of complexes measured in CH
3CN solutions versus different reference electrodes. A critical review of conversion constants amongst various reference electrodes reported in the literature reveals that in most cases the comparisons of redox potential values are far from accurate. From measurements of relationships amongst various common reference electrodes in CH
3CN solutions, conversion constants for redox potentials measured versus different reference electrodes in acetonitrile solutions at 25°C are proposed, along with a convention for reporting redox potential values.
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Details
- Title
- Conversion constants for redox potentials measured versus different reference electrodes in acetonitrile solutions at 25°C
- Creators
- Vitaly V Pavlishchuk - L.V. Pisarzhevskii Institute of Physical ChemistryAnthony W Addison - Drexel University
- Publication Details
- Inorganica Chimica Acta, v 298(1)
- Publisher
- Elsevier
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- Chemistry
- Web of Science ID
- WOS:000085017600016
- Scopus ID
- 2-s2.0-0034731723
- Other Identifier
- 991019168696204721
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- Collaboration types
- Domestic collaboration
- International collaboration
- Web of Science research areas
- Chemistry, Inorganic & Nuclear