Journal article
Correlation between the electrochemical response and main components structure in solutions for rechargeable Mg batteries based on THF and the reaction products of tBuMgCl and AlCl3
Electrochimica acta, v 454, 142413
20 Jun 2023
Abstract
•We explore here the products of the reaction of the Grignard reagent t-BuMgCl with AlCl3 (1:1) in THF, and how their presence in solutions affect their electrochemical behavior.•Two complex products were isolated from the precipitated part of the reaction and the counter solution part, which exhibit two distinct single-crystal structures.•Crystallization from precipitated part (compound I) has the molecular structure [MgCl·THF5]+ [AlCl4]– and it is electrochemically inactive in terms of reversible Mg dissolution/deposition.•The molecular structure of the second compound (II), obtained from solution part is [Mg2(μ-Cl)3·THF6]+ [t-BuAlCl3]- and its solutions in THF exhibit reversible Mg dissolution/deposition behavior.•This study demonstrates the possibility of tuning judiciously the electrochemical response of ethereal solutions of magnesium organohaloaluminate complexes through their structural modifications.
The electrochemical response of ethereal solutions containing magnesium organohaloaluminate complexes has drawn great interest in recent decades owing to their relevance to rechargeable magnesium batteries, as demonstrated with solutions containing complexes formed by reacting R2Mg and AlCl2R moieties in ethers like tetrahydrofuran (THF). However, most of previous reports focused on battery related performances, and less on the structure of the active species. Herein, we focus on (1) identifying electroactive species and (2) correlating the electrochemical properties of their solutions to the preparation modes: either through reactions of their precursors in THF, or by dissolving isolated crystallized products in the ether solvent. Specifically, we explore the products of the reaction of the Grignard reagent t-BuMgCl with AlCl3 (1:1) in THF, and how their presence in solutions affect their electrochemical behavior.
We isolated two complex products, one non-soluble and one soluble in THF, which exhibit two distinct single-crystal structures. The molecular structure of the two complexes obtained from the single-crystal X-ray diffraction (SCXRD) and nuclear magnetic resonance (NMR) measurements was correlated with the electrochemical behavior of their solutions in THF, as reflected by their cyclic voltammetry (CV) response. We found that one product (compound I) has the molecular structure [MgCl·THF5]+ [AlCl4]– and it is electrochemically inactive in terms of reversible Mg dissolution/deposition. The molecular structure of the second compound (II), [Mg2(μ-Cl)3·THF6]+ [t-BuAlCl3]–, has not been reported before, and its solutions in THF exhibit reversible Mg dissolution/deposition behavior. Our study clearly demonstrates the possibility of tuning judiciously the electrochemical response of ethereal solutions of magnesium organohaloaluminate complexes through their structural modifications.
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Details
- Title
- Correlation between the electrochemical response and main components structure in solutions for rechargeable Mg batteries based on THF and the reaction products of tBuMgCl and AlCl3
- Creators
- Sankalpita Chakrabarty - Bar-Ilan UniversityYuri Glagovsky - Technion – Israel Institute of TechnologyAnanya Maddegalla - Bar-Ilan UniversityNatalia Fridman - Technion – Israel Institute of TechnologyDmitry Bravo-Zhivotovski - Technion – Israel Institute of TechnologyDoron Aurbach - Bar-Ilan UniversityAyan Mukherjee - Bar-Ilan UniversityMalachi Noked - Bar-Ilan University
- Publication Details
- Electrochimica acta, v 454, 142413
- Publisher
- Elsevier
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- Mechanical Engineering and Mechanics
- Web of Science ID
- WOS:000990624400001
- Scopus ID
- 2-s2.0-85152598651
- Other Identifier
- 991022004621004721
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- Collaboration types
- Domestic collaboration
- International collaboration
- Web of Science research areas
- Electrochemistry