Mechanically robust, non-toxic polymer fiber mats are promising materials for a range of biomedical applications; however, further research into enhancing polymer selection is needed. In this study, poly(allylamine) (PAH), an amine-containing polyelectrolyte, was successfully electrospun from aqueous solutions into continuous, cylindrical fibers with a mean diameter of 150 +/- A 41 nm. A one-step crosslinking method using glutaraldehyde provides insight into the chemical and morphological changes that result from altering the molar ratio of amine to aldehyde groups, whereas a two-step crosslinking method yielded chemically and mechanically robust mats. These results indicate PAH fibrous mats synthesized from aqueous solutions could potentially be applied in biomedical applications.
Crosslinking poly(allylamine) fibers electrospun from basic and acidic solutions
Creators
Jessica D. Schiffman - University of Massachusetts Amherst
Marjorie A. Kiechel - Drexel University
Amalie E. Donius - Drexel University
Ulrike G. K. Wegst - Dartmouth College
Caroline L. Schauer - Drexel University
Publication Details
Journal of materials science, v 48(22), pp 7856-7862
Publisher
Springer Nature
Number of pages
7
Grant note
0804543 / NSF CMMI; National Science Foundation (NSF)
Drexel University Freshmen Design Engineering Fellowship
0654313 / NSF-IGERT; National Science Foundation (NSF)
Institute of Food Technologists-Philadelphia Chapter
Ben Franklin Nanotechnology Institute, Philadelphia, PA
0907572 / NSF DMR; National Science Foundation (NSF)
P200A070496 / GAANN Fellowship; US Department of Education
P200A060117 / Department of Education's Office of Postsecondary Education; US Department of Education
Resource Type
Journal article
Language
English
Academic Unit
Materials Science and Engineering
Web of Science ID
WOS:000323503900009
Scopus ID
2-s2.0-84883146463
Other Identifier
991019168478604721
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