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Journal article
Crystal structure of bis(pivaloylhydroxamato kappa O-2, O ') copper(II)
Acta crystallographica. Section E, Crystallographic communications, v 74(Pt 9), pp 1384-1387
01 Sep 2018
PMID: 30225137
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Abstract
Reaction of copper(II) nitrate with pivaloylhydroxamic acid yielded the title compound, [Cu(pivHA)(2)] (where pivHA(-) is pivaloyl hydroxamate, C5H10NO2). The centrosymmetric mononuclear complex consists of a Cu II ion, which is located on a center of inversion, with two coordinated pivaloyl hydroxamate monoanions. The Cu II ion has a square-planar coordination environment consisting of four O atoms - two carbonyl O atoms and two hydroxamate O atoms from two hydroxamate pivHA(-) ligands. The pivHA(-) anions are coordinated to copper(II) in a trans-mode, forming two five-membered O, O'-chelate rings.
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Details
- Title
- Crystal structure of bis(pivaloylhydroxamato kappa O-2, O ') copper(II)
- Creators
- Kateryna Goleva - Taras Shevchenko National University of KyivDina Naumova - Taras Shevchenko National University of KyivAnna Pavlishchuk - Taras Shevchenko National University of KyivAnthony W. Addison - Drexel UniversityMatthias Zeller - Purdue University West Lafayette
- Publication Details
- Acta crystallographica. Section E, Crystallographic communications, v 74(Pt 9), pp 1384-1387
- Publisher
- Int Union Crystallography
- Number of pages
- 7
- Grant note
- 1337296 / National Science Foundation, Division of Materials Research; National Science Foundation (NSF)
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- Chemistry
- Web of Science ID
- WOS:000443407400042
- Scopus ID
- 2-s2.0-85053072730
- Other Identifier
- 991019168823704721
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- Collaboration types
- Domestic collaboration
- International collaboration
- Web of Science research areas
- Crystallography