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Design and Synthesis of the Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material Ba-3(ZnB5O10)PO4
Journal article   Peer reviewed

Design and Synthesis of the Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material Ba-3(ZnB5O10)PO4

Hongwei Yu, Weiguo Zhang, Joshua Young, James M. Rondinelli and P. Shiv Halasyamani
Advanced materials (Weinheim), v 27(45), p7380
02 Dec 2015
PMID: 26459262

Abstract

Chemistry Chemistry, Multidisciplinary Chemistry, Physical Materials Science Materials Science, Multidisciplinary Nanoscience & Nanotechnology Physical Sciences Physics Physics, Applied Physics, Condensed Matter Science & Technology Science & Technology - Other Topics Technology
Access to the elusive deep-ultraviolet by direct second harmonic generation (SHG) enabled by a new beryllium-free zincoborate-phosphate crystal is reported. Ba-3(ZnB5O10)PO4, exhibits large SHG responses at 1064 and 532 nm and a short 180 nm absorption edge. Centimeter-size crystals are grown, and quantum mechanical calculations demonstrate the key role played by ZnO4 tetrahedra in the enhanced optical responses.

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Collaboration types
Domestic collaboration
Web of Science research areas
Chemistry, Multidisciplinary
Chemistry, Physical
Materials Science, Multidisciplinary
Nanoscience & Nanotechnology
Physics, Applied
Physics, Condensed Matter
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