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Dielectric Barrier Discharge Plasma Polymerization of N-Vinylimidazole: Structural Characterization and Cr3+ Coordination Behavior
Journal article   Open access   Peer reviewed

Dielectric Barrier Discharge Plasma Polymerization of N-Vinylimidazole: Structural Characterization and Cr3+ Coordination Behavior

Nuri Simone Ferguson and Hai-Feng (Frank) Ji
Polymers, v 18(11), 1332
28 May 2026
DOI: https://doi.org/10.3390/polym18111332
PMID: 42280544
Featured in Collection :   Research Supported by Drexel Libraries' OA Programs
url
https://doi.org/10.3390/polym18111332View
Published, Version of Record (VoR) Open Access Discount via Drexel Libraries Read and Publish Program 2026 Open CC BY V4.0

Abstract

atmospheric-pressure plasma dielectric barrier discharge plasma polymerization N-vinylimidazole poly(N-vinylimidazole) chromium(III) coordination Polymeric Materials
Plasma polymerization offers a solvent-free route to functional polymer materials, but the structural integrity and accessibility of functional groups in plasma-derived networks remain insufficiently validated. Herein, N-vinylimidazole (NVI) was polymerized using atmospheric-pressure dielectric barrier discharge (DBD) plasma in a liquid-film configuration to generate a chemically heterogeneous poly(N-vinylimidazole)-like material that could be recovered and evaluated in aqueous solution. ATR–FTIR and 1H NMR spectroscopy indicate substantial vinyl-group consumption with retention of imidazole functionality. Functional behavior was probed using chromium(III) (Cr3+) as a model metal ion. UV–Vis spectroscopy revealed systematic changes in the Cr3+ d–d transition region (~580–600 nm) with increasing polymer concentration, consistent with ligand-field perturbation arising from interactions with imidazole donor sites. A monotonic increase in absorbance with an increasing ligand-to-metal ratio was observed, followed by plateau behavior at higher ratios, indicating saturation of accessible coordination environments. These results demonstrate that plasma-polymerized material retains chemically accessible imidazole functionalities capable of coordinating transition-metal ions in solution, establishing atmospheric-pressure plasma polymerization as a viable route to functional imidazole-containing materials.

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