Journal article
Dramatic tuning of ligand donor properties in (Ttz)CuCO through remote binding of H+ (Ttz = hydrotris(triazolyl)borate)
Chemical communications (Cambridge, England), v 49(49), pp 5571-5573
01 Jan 2013
PMID: 23675583
Featured in Collection : UN Sustainable Development Goals @ Drexel
Abstract
Complexes with bulky hydrotris(triazolyl) borate (Ttz) ligands, TtzCuCO, were used to probe how acids change the donor properties of Ttz ligands. (Ttz(tBu,Me))CuCO shows four distinct protonation states and a gradual increase in the CO stretch. The increased electrophilic nature of the Cu center upon protonation leads to enhanced C-H activation catalysis.
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Details
- Title
- Dramatic tuning of ligand donor properties in (Ttz)CuCO through remote binding of H+ (Ttz = hydrotris(triazolyl)borate)
- Creators
- Natalie A. Dixon - Drexel UniversityAshley B. McQuarters - University of Michigan–Ann ArborJodi S. Kraus - Drexel UniversityJonathan B. Soffer - Drexel UniversityNicolai Lehnert - University of Michigan–Ann ArborReinhard Schweitzer-Stenner - Drexel UniversityElizabeth T. Papish - Drexel University
- Publication Details
- Chemical communications (Cambridge, England), v 49(49), pp 5571-5573
- Publisher
- Royal Soc Chemistry
- Number of pages
- 3
- Grant note
- CHE-0846383 / NSF CAREER; National Science Foundation (NSF); NSF - Office of the Director (OD) NTFG 5286067 / 3M
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- [Retired Faculty]
- Web of Science ID
- WOS:000319406300015
- Scopus ID
- 2-s2.0-84879490429
- Other Identifier
- 991019167784804721
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- Collaboration types
- Domestic collaboration
- Web of Science research areas
- Chemistry, Multidisciplinary