Journal article
Effect of Fullerene Volume Fraction on Two-Dimensional Crystal-Constructed Supramolecular Liquid Crystals
Chemistry, an Asian journal, v 14(1)
04 Jan 2019
PMID: 30371012
Featured in Collection : UN Sustainable Development Goals @ Drexel
Abstract
The volume fraction plays an important role in phase segregated soft matters. We demonstrate here that at high fullerene volume fraction in soft chain-tethered-fullerene dyads, different two-dimensional (2D) crystal-constructed smectic-like lamella liquid crystalline (LC) phases can be formed with triple-layer (S
phase) or quadruple-layer (S
phase) stacking of fullerenes in 2D crystals. The combination of 2D crystal and LC properties in one system affords these fullerene dyads controlled electron mobility in the range of 10
-10
cm
V
s
at room temperature (S
phase), by regulating the insulated soft layer thickness between 2D crystals via the manipulation of fullerene volume fraction.
Metrics
Details
- Title
- Effect of Fullerene Volume Fraction on Two-Dimensional Crystal-Constructed Supramolecular Liquid Crystals
- Creators
- Peng Shen - Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, P. R. ChinaXiaoyan Zhang - Institute of Biomedical Materials and Engineering, College of Materials Science and Engineering, Qingdao University, Qingdao, 266071, P. R. ChinaHuanjun Lu - Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, P. R. ChinaZebin Su - Department of Polymer Science, College of Polymer Science and Polymer Engineering, University of Akron, Akron, OH, 44325, USAYi Zhou - Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, P. R. ChinaBo Song - Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, P. R. ChinaXiaohong Li - Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, P. R. ChinaXiaoming Yang - Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, P. R. ChinaYingfeng Tu - Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, P. R. ChinaChristopher Y Li - Department of Materials Science and Engineering, Drexel University, Philadelphia, PA, 19104, USA
- Publication Details
- Chemistry, an Asian journal, v 14(1)
- Publisher
- Wiley; Germany
- Grant note
- 21774090, 21474067 / National Natural Science Foundation of China
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- Materials Science and Engineering
- Web of Science ID
- WOS:000454953700011
- Scopus ID
- 2-s2.0-85057540902
- Other Identifier
- 991014878236004721
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- Collaboration types
- Domestic collaboration
- International collaboration
- Web of Science research areas
- Chemistry, Multidisciplinary