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Effect of a dielectric coating on quenching in a molecule-nanosphere system
Journal article   Peer reviewed

Effect of a dielectric coating on quenching in a molecule-nanosphere system

Alessia Polemi and Kevin L. Shuford
Chemical physics letters, v 546, pp 129-132
12 Sep 2012
url
http://hdl.handle.net/11380/1011734View
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Abstract

Chemistry Chemistry, Physical Physical Sciences Physics Physics, Atomic, Molecular & Chemical Science & Technology
We investigate the effect a dielectric coating has on the energy transfer between a molecule and a silver nanosphere. For a fixed wavelength excitation resonant with the bare nanoparticle, increasing the shell thickness increases the non-radiative decay rate and decreases the radiative decay rate, which decreases the total efficiency of the emission process. The excitation wavelength can be tuned to improve the efficiency for coated nanoparticles, leading to values that are comparable to bare nanoparticles. As such, dielectric coatings are able to effectively limit quenching without sacrificing efficiency. (C) 2012 Elsevier B.V. All rights reserved.

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Collaboration types
Domestic collaboration
International collaboration
Web of Science research areas
Chemistry, Physical
Physics, Atomic, Molecular & Chemical
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