Logo image
Effect of membrane characteristics on phase separation and domain formation in cholesterol-lipid mixtures
Journal article   Open access   Peer reviewed

Effect of membrane characteristics on phase separation and domain formation in cholesterol-lipid mixtures

Veena Pata and Nily Dan
Biophysical journal, v 88(2), pp 916-924
Feb 2005
PMID: 15542557
url
https://doi.org/10.1529/biophysj.104.052241View
Published, Version of Record (VoR)Open Access (Publisher-Specific) Open

Abstract

Cholesterol - chemistry Complex Mixtures - chemistry Computer Simulation Lipid Bilayers - chemistry Macromolecular Substances - chemistry Membrane Fluidity Membrane Microdomains - chemistry Membranes, Artificial Models, Chemical Models, Molecular Molecular Conformation Phase Transition
We examine, using an analytical mean-field model, the distribution of cholesterol in a lipid bilayer. The model accounts for the perturbation of lipid packing induced by the embedded cholesterol, in a manner similar to that of transmembrane proteins. We find that the membrane-induced interactions between embedded cholesterol molecules vary as a function of the cholesterol content. Thus, the effective lipid-cholesterol interaction is concentration-dependent. Moreover, it transitions from repulsive to attractive to repulsive as the cholesterol content increases. As the concentration of cholesterol in the bilayer exceeds a critical value, phase separation occurs. The coexistence between cholesterol-rich and cholesterol-poor domains is universal for any bilayer parameters, although the composition of the cholesterol-rich phase varies as a function of the lipid properties. Although we do not assume specific cholesterol-lipid interactions or the formation of a lipid-cholesterol cluster, we find that the composition of the cholesterol-rich domains is constant, independent of the cholesterol content in the bilayer.

Metrics

7 Record Views
21 citations in Scopus

Details

UN Sustainable Development Goals (SDGs)

This publication has contributed to the advancement of the following goals:

#3 Good Health and Well-Being

InCites Highlights

Data related to this publication, from InCites Benchmarking & Analytics tool:

Web of Science research areas
Biophysics
Logo image