Herein, we demonstrate the fabrication of Ti3C2Tx MXene films using electrophoretic deposition (EPD). A systematic study under constant voltage conditions from aqueous and propylene carbonate-based suspensions was performed to investigate the effects of the EPD process parameters on film morphology, flake orientation, and functional properties. From measured suspension properties, the kinetics of deposition from both suspension media were successfully described by the well-established Sarkar model of EPD. Remarkably, EPD-processed films have electrical conductivities of 7400 S/cm, on par with the highest values reported in the literature for Ti3C2Tx MXene. When employed as electrochemical capacitor electrodes in 1 M H2SO4, the capacitances were comparable to literature values. Given the process scalability and the morphological control that is possible, these results bode well for EPD as a fast, high-throughput method for making MXene films. (C) The Author(s) 2017. Published by ECS. All rights reserved.
Electrophoretic Deposition of Two-Dimensional Titanium Carbide (MXene) Thick Films
Creators
Pieralberto Collini - Drexel University
Sankalp Kota - Drexel University
Andrew D. Dillon - Drexel University
Michel W. Barsoum - Drexel University
Aaron T. Fafarman - Drexel University
Publication Details
Journal of the Electrochemical Society, v 164(9), pp D573-D580
Publisher
Electrochemical Soc Inc
Number of pages
8
Grant note
1463412 / Div Of Civil, Mechanical, & Manufact Inn; National Science Foundation (NSF); NSF - Directorate for Engineering (ENG)
CMMI-1463412 / Civil, Mechanical and Manufacturing Innovation Division of the National Science Foundation (NSF)
DMR-1310245 / Division of Materials Research; National Science Foundation (NSF); NSF - Directorate for Mathematical & Physical Sciences (MPS)
Resource Type
Journal article
Language
English
Academic Unit
Materials Science and Engineering; Chemical and Biological Engineering
Web of Science ID
WOS:000413256400025
Scopus ID
2-s2.0-85042372728
Other Identifier
991019167858904721
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