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Enhancing the photoluminescence of SnS quantum dots by ZnS treatment
Journal article   Peer reviewed

Enhancing the photoluminescence of SnS quantum dots by ZnS treatment

Huai-Yu Cheng, Ozgun Acar, Wan Y. Shih and Wei-Heng Shih
Chemical physics letters, v 754, 137696
Sep 2020

Abstract

Coating Near-infrared Nontoxic Quantum dots Tin sulfide Zinc sulfide
[Display omitted] •Tin sulfide (SnS) quantum dots were surface treated with Zinc Sulfide (ZnS) precursors.•Surface treatment increased SnS QD photoluminescence by 20x without affecting emission wavelength.•Improved stability of SnS/ZnS QD suspensions in glycerol in a wide pH range with mercaptopropionic acid (MPA)•Improved stability of SnS/ZnS QD in aqueous suspensions using mercaptopropylsilane (MPS) Near-infrared, nontoxic SnS quantum dot has been shown to be a good bioimaging probe. It was found that surface treatment by ZnS precursor solution improved the photoluminescence of the SnS by 19x without changing the emission wavelength. EDS and XPS showed that small amounts of ZnS was present on the surface of SnS particles, while TEM showed that the ZnS treatment caused the SnS particles to cluster leading to a redshift in the UV/Vis absorption spectra and the sharpening of XRD peaks. The suspension stability of the SnS/ZnS quantum dots was further improved with 3-Mercaptopropionic acid as a capping molecule.

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Web of Science research areas
Chemistry, Physical
Physics, Atomic, Molecular & Chemical
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