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Evaluation of core–shell particle columns for ion-pair reversed-phase liquid chromatography analysis of oligonucleotides
Journal article   Peer reviewed

Evaluation of core–shell particle columns for ion-pair reversed-phase liquid chromatography analysis of oligonucleotides

Mirlinda Biba, Christopher J Welch, Joe P Foley, Bing Mao, Enrique Vazquez and Rebecca A Arvary
Journal of pharmaceutical and biomedical analysis, v 72
18 Jan 2013
PMID: 23146223

Abstract

siRNA Sub-2 μm core-shell columns Core–shell particle columns Ion-pair reversed-phase liquid chromatography Oligonucleotides
► Oligonucleotide analysis by ion-pair reversed-phase liquid chromatography. ► Evaluation of different fused-core columns for oligonucleotide analysis. ► Fused-core columns provided improved separations of oligonucleotides. ► The sub-2μm particle fused-core columns showed the best separations. ► Long term column stability was tested for fused-core columns. An investigation into the use of core–shell particle columns for separation of short (∼21 base pairs) RNA oligonucleotides by ion-pair reversed-phase liquid chromatography (IP-RPLC) showed improved resolution for a number of test analytes relative to conventional (fully-porous) reversed-phase columns. The best resolutions were obtained using columns packed with smaller sub-2μm core–shell particles.

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Collaboration types
Industry collaboration
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Web of Science research areas
Chemistry, Analytical
Pharmacology & Pharmacy
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