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Fluorinated Colloidal Emulsion of Photochangeable Rheological Behavior as a Sacrificial Agent to Fabricate Organic, Three-Dimensional Microstructures
Journal article   Peer reviewed

Fluorinated Colloidal Emulsion of Photochangeable Rheological Behavior as a Sacrificial Agent to Fabricate Organic, Three-Dimensional Microstructures

Li-Hsin Han, Jeffrey A. Easley, Christopher J. Ellison and Shaochen Chen
Langmuir, v 26(9), pp 6108-6110
04 May 2010
PMID: 20349967

Abstract

Chemistry Chemistry, Multidisciplinary Chemistry, Physical Materials Science Materials Science, Multidisciplinary Physical Sciences Science & Technology Technology
Three-dimensional organic microfabrication, an emerging technology, faces the challenge of lacking it sacrificial agent (SA) to temporarily support the formation of microscale geometries, which can he removed after a microstructure is constructed. In this study. an ultradense oil-in-organofluorine colloidal emulsion with photopolymerizable submicrometer droplets (diameter similar to 500 nm) was prepared and used as die required SA. Upon exposure to light, the colloidal emulsion undergoes a significant rheological change, which hardens the emulsion and presents the molding/protecting function that an SA must have. Importantly, the emulsion includes a synthesized fluorophilic/fluorophobic block copolymer surfactant to stabilize the droplet compartments, facilitating the dissolution of the postexposure SA. Two successfully built, complex, organic 3D microstructures show the effectiveness of using this novel SA material.

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Web of Science research areas
Chemistry, Multidisciplinary
Chemistry, Physical
Materials Science, Multidisciplinary
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