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Formation and [3,3]-sigmatropic rearrangement of O-allyl nitronic esters: a new route to gamma,delta-unsaturated nitro compounds
Journal article

Formation and [3,3]-sigmatropic rearrangement of O-allyl nitronic esters: a new route to gamma,delta-unsaturated nitro compounds

Peter A Wade, Alma Pipic, Manikandan Santhanaraman and Hung T Le
Chemical communications (Cambridge, England), (24), pp 3531-3532
28 Jun 2009
PMID: 19521597

Abstract

O-Allyl nitronic esters that are obtained from tin(IV) catalyzed Diels-Alder reactions undergo thermal rearrangement to gamma,delta-unsaturated nitro compounds.

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Chemistry, Multidisciplinary
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