Journal article
Formation of ammonia from an iron nitrido complex
Angewandte Chemie (International ed.), v 48(17), pp 3158-3160
01 Jan 2009
PMID: 19322861
Featured in Collection : UN Sustainable Development Goals @ Drexel
Abstract
Radical ideas: Reaction of the iron(IV) nitrido complex [PhB(MesIm)(3)Fe[triple chemical bond]N] (see picture, Mes=2,4,6-Me(3)C(6)H(2)) with TEMPO-H (1-hydroxy-2,2,6,6-tetramethylpiperidine) results in high yields of ammonia and quantitative formation of [PhB(MesIm)(3)Fe(tempo)]. The mechanism likely involves hydrogen-atom transfer from TEMPO-H to the nitrido complex. Similar reaction with the triphenylmethyl radical yields [PhB(MesIm)(3)Fe[triple chemical bond]N--CPh(3)].
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Details
- Title
- Formation of ammonia from an iron nitrido complex
- Creators
- Jeremiah J Scepaniak - New Mexico State UniversityJessica A Young - New Mexico State UniversityRanko P Bontchev - Cabot (United States)Jeremy M Smith - New Mexico State University
- Publication Details
- Angewandte Chemie (International ed.), v 48(17), pp 3158-3160
- Publisher
- Wiley
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- Chemistry
- Web of Science ID
- WOS:000265465200032
- Scopus ID
- 2-s2.0-70349782204
- Other Identifier
- 991020902865704721
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InCites Highlights
Data related to this publication, from InCites Benchmarking & Analytics tool:
- Web of Science research areas
- Chemistry, Multidisciplinary