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Formation of filamentous carbon from paraformaldehyde under high temperatures and pressures
Journal article   Peer reviewed

Formation of filamentous carbon from paraformaldehyde under high temperatures and pressures

Yury G Gogotsi and Klaus G Nickel
Carbon (New York), v 36(7), pp 937-942
1998

Abstract

C. Raman spectroscopy A. Carbon filaments C. Hydrothermal synthesis C. thermodynamic simulation
Synthesis of filamentous carbon from paraformaldehyde by high-temperature, high-pressure treatment under “hydrothermal” conditions is reported. Deposition of carbon started at about 600 °C. Carbon filaments were grown at 650–750 °C. Raman and X-ray diffraction studies demonstrated the amorphous structure and sp 2 bonding of carbon in the filaments. Their length and thickness depended upon the experimental conditions. Well-ordered graphite was found at 800 °C. Thermodynamic calculations of the decomposition of formaldehyde under high temperatures and high pressures were also carried out. The results of the thermodynamic and experimental study are compared.

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Collaboration types
Domestic collaboration
International collaboration
Web of Science research areas
Chemistry, Physical
Materials Science, Multidisciplinary
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