Journal article
Formation of filamentous carbon from paraformaldehyde under high temperatures and pressures
Carbon (New York), Vol.36(7), pp.937-942
1998
Abstract
Synthesis of filamentous carbon from paraformaldehyde by high-temperature, high-pressure treatment under “hydrothermal” conditions is reported. Deposition of carbon started at about 600 °C. Carbon filaments were grown at 650–750 °C. Raman and X-ray diffraction studies demonstrated the amorphous structure and sp
2 bonding of carbon in the filaments. Their length and thickness depended upon the experimental conditions. Well-ordered graphite was found at 800 °C. Thermodynamic calculations of the decomposition of formaldehyde under high temperatures and high pressures were also carried out. The results of the thermodynamic and experimental study are compared.
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Details
- Title
- Formation of filamentous carbon from paraformaldehyde under high temperatures and pressures
- Creators
- Yury G Gogotsi - Department of Mechanical Engineering, University of Illinois at Chicago, 842 West Taylor Street, Chicago, IL 60607-7022 U.S.AKlaus G Nickel - Institut für Mineralogie, Petrologie und Geochemie, Universität Tübingen, Wilhelmstr. 56, D-72074 Tübingen, Germany
- Publication Details
- Carbon (New York), Vol.36(7), pp.937-942
- Publisher
- Elsevier
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- Materials Science and Engineering
- Identifiers
- 991014969888604721
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- Collaboration types
- Domestic collaboration
- International collaboration
- Web of Science research areas
- Chemistry, Physical
- Materials Science, Multidisciplinary