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Formulation of a Model Resin System for Benchmarking Processing-Property Relationships in High-Performance Photo 3D Printing Applications
Journal article   Open access   Peer reviewed

Formulation of a Model Resin System for Benchmarking Processing-Property Relationships in High-Performance Photo 3D Printing Applications

Jianwei Tu, Kamran Makarian, Nicolas J. Alvarez and Giuseppe R. Palmese
Materials, v 13(18), p4109
01 Sep 2020
PMID: 32947908
url
https://doi.org/10.3390/ma13184109View
Published, Version of Record (VoR)CC BY V4.0 Open

Abstract

Chemistry Chemistry, Physical Materials Science Materials Science, Multidisciplinary Metallurgy & Metallurgical Engineering Physical Sciences Physics Physics, Applied Physics, Condensed Matter Science & Technology Technology
A well-defined resin system is needed to serve as a benchmark for 3D printing of high-performance composites. This work describes the design and characterization of such a system that takes into account processability and performance considerations. The Grunberg-Nissan model for resin viscosity and the Fox equation for polymer T-g were used to determine proper monomer ratios. The target viscosity of the resin was below 500 cP, and the target final T-g of the cured polymer was 150 degrees C based on tan-delta peak from dynamic mechanical analysis. A tri-component model resin system, termed DA-2 resin, was determined and fully characterized. The printed polymer exhibited good thermal properties and high mechanical strength after post-cure, but has a comparatively low fracture toughness. The model resin will be used in additive manufacturing of fiber reinforced composite materials as well as for understanding the fundamental processing-property relationships in light-based 3D printing.

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37 citations in Scopus

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Web of Science research areas
Chemistry, Physical
Materials Science, Multidisciplinary
Metallurgy & Metallurgical Engineering
Physics, Applied
Physics, Condensed Matter
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