Logo image
From multi-ring to spider web and radial spoke: competition between the receding contact line and particle deposition in a drying colloidal drop
Journal article

From multi-ring to spider web and radial spoke: competition between the receding contact line and particle deposition in a drying colloidal drop

Xin Yang, Christopher Y. Li and Ying Sun
Soft matter, v 10(25), pp 4458-4463
01 Jan 2014
PMID: 24819228

Abstract

Chemistry Chemistry, Physical Materials Science Materials Science, Multidisciplinary Physical Sciences Physics Physics, Multidisciplinary Polymer Science Science & Technology Technology
Deposition morphologies of inkjet-printed colloidal drops are examined under various drying conditions, particle volume fractions, and particle sizes. Concentric multi-rings, radial spokes, spider web, foam, and island-like depositions are observed as a result of the competition between the receding contact line and particle deposition during drop drying. Experimentally measured multi-ring spacing, delta R, shows good agreement with the model predicted linear correlation with the local ring radius R. The results also show that the instability near the contact line leads to the radial spoke and saw-toothed structures. The resulting wavelength of the radial structures, lambda, satisfies lambda similar to 3 root R and lambda similar to 1/3 root 1 - RH, where RH is the relative humidity. A dimensionless parameter xi, defined as the radial deposition growth rate to contact line velocity ratio, has been identified to determine the conditions under which the entire contact line can be pinned to leave a continuous ring deposit. Increasing the particle size while keeping the volume fraction the same is found to suppress the formation of the multi-ring deposition, due to a smaller number of particles available to pin the receding contact line.

Metrics

3 Record Views
36 citations in Scopus

Details

UN Sustainable Development Goals (SDGs)

This publication has contributed to the advancement of the following goals:

#6 Clean Water and Sanitation

InCites Highlights

Data related to this publication, from InCites Benchmarking & Analytics tool:

Web of Science research areas
Chemistry, Physical
Materials Science, Multidisciplinary
Physics, Multidisciplinary
Polymer Science
Logo image