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Generation and in situ Diels–Alder reactions of activated nitroethylene derivatives
Journal article   Peer reviewed

Generation and in situ Diels–Alder reactions of activated nitroethylene derivatives

Peter A. Wade, James K. Murray, Sharmila Shah-Patel and Patrick J. Carroll
Tetrahedron letters, v 43(14), pp 2585-2588
2002

Abstract

Dienes readily undergo Diels–Alder reaction with CH 2C(NO 2)SO 2Ph ( 2a ), CH 2C(NO 2)CO 2Et ( 2b ), and CH 2C(NO 2)COPh ( 2c ), all observed in situ by 1H NMR. The cycloadducts of 2a undergo S RN1 reactions. Activated nitroethylene derivatives can be easily generated and used in situ for Diels–Alder reactions.

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Collaboration types
Domestic collaboration
Web of Science research areas
Chemistry, Organic
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