Journal article
High-Capacity Li-ion Battery Anode Made of Tin (II) Selenide with Ti3C2T MXene Binder
Energy Storage Materials, v 83, 104675
Dec 2025
Abstract
Developing next-generation anode materials is crucial for advancing lithium-ion batteries, particularly in terms of capacity, safety, and cycling stability. While tin (II) selenide (SnSe) boasts a high theoretical capacity, its practical application is hindered by poor stability and volume expansion during cycling. To address these challenges, we combined commercially available SnSe with Ti3C2Tx MXene, which shows metallic conductivity and excellent binding properties. This study shows that a composite anode comprising SnSe and Ti3C2Tx needs no additional additives and has a minimal dead volume. Electrochemical evaluation demonstrated that our composite outperforms traditional anode materials due to the intrinsic MXene pseudo-capacitance and redox activity. The composite reached 918 mAh/g(total) (1148 mAh/g(SnSe)) at 0.2 C for 170 cycles and 720 mAh/g(total) (900 mAh/g(SnSe)) at 150 cycles at charge-discharge rates of 0.2 C and 0.5 C, respectively. This makes our hybrid structure a promising candidate for high-performance energy storage devices.
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Details
- Title
- High-Capacity Li-ion Battery Anode Made of Tin (II) Selenide with Ti3C2T MXene Binder
- Creators
- Kavin Arunasalam - Trinity College DublinJesus Medina Santos - Trinity College DublinXuyun Guo - Trinity College DublinLee Gannon - Trinity College DublinStefano Ippolito - Drexel UniversityTeng Zhang - Drexel UniversityDahnan Spurling - Trinity College DublinÉanna McCarthy - Dublin City UniversityRob O'Connor - Dublin City UniversityDermot Brabazon - Dublin City UniversityCormac McGuinness - Trinity College DublinYury Gogotsi - Drexel UniversityValeria Nicolosi (Corresponding Author) - Trinity College Dublin
- Publication Details
- Energy Storage Materials, v 83, 104675
- Publisher
- Elsevier
- Number of pages
- 12
- Grant note
- Research Ireland Centre for Doctoral Training in Advanced Characterisation of Materials (CDT-ACM): 18/EPSRC-CDT-3581 RI AMBERRI Frontiers for the Future: 12/RC/2278_P2, 20/FFPA/8950 Taighde Eireann - Research Ireland: GOIPG-/2020/1250 U.S. Department of Energy (DOE) , Office of Science, Office of Basic Energy Sciences: DE-SC0018618 Army Research Laboratory for MXene development and characterization accomplished: W911NF-19-2-0119 AMBER Research CentreFrontiers for the Future award: 12/RC/2278_P2, 20/FFP-A/8950
K.A. and V.N. acknowledge funding from Research Ireland Centre for Doctoral Training in Advanced Characterisation of Materials (CDT-ACM) (Award Reference 18/EPSRC-CDT-3581) . J.M. acknowledges financial support from RI AMBER and RI Frontiers for the Future through two grants from Research Ireland under Grant Nos. 12/RC/2278_P2 and 20/FFPA/8950. L.G. acknowledges funding from Taighde Eireann - Research Ireland under Grant No. GOIPG-/2020/1250. S.I., T. Z., and Y.G. acknowledge support from the U.S. Department of Energy (DOE) , Office of Science, Office of Basic Energy Sciences, Grant No. DE-SC0018618. S.I. and Y.G. also acknowledge the Army Research Laboratory for MXene development and characterization accomplished under Cooperative Agreement No. W911NF-19-2-0119. V.N. and X.G. wish to thank the support of the Research Ireland-funded AMBER Research Centre and the Frontiers for the Future award (Grant Nos. 12/RC/2278_P2 and 20/FFP-A/8950, respectively) . Furthermore, K.A., X. G., and V.N. wish to thank the Advanced Microscopy Laboratory (AML) in CRANN for the provision of their facilities.
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- Materials Science and Engineering; A.J. Drexel Nanomaterials Institute
- Web of Science ID
- WOS:001603209400002
- Scopus ID
- 2-s2.0-105022151486
- Other Identifier
- 991022123507204721
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- Collaboration types
- Domestic collaboration
- International collaboration
- Web of Science research areas
- Chemistry, Physical
- Materials Science, Multidisciplinary
- Nanoscience & Nanotechnology