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High-pressure x-ray diffraction study of Ta 4 Al C 3
Journal article   Peer reviewed

High-pressure x-ray diffraction study of Ta 4 Al C 3

Bouchaib Manoun, S Saxena, T El-Raghy and M Barsoum
Applied physics letters, v 88(20), pp 201902-201902-3
15 May 2006

Abstract

Using a synchrotron radiation source and a diamond anvil cell, we measured the pressure dependence of the lattice parameters of a recently discovered phase, Ta 4 Al C 3 . This phase adopts a hexagonal structure with the space group P 6 3 ∕ mmc ; at room conditions, the a and c parameters are 3.087(5) and 23.70 ( 4 ) Å , respectively. Up to a pressure of 47 GPa , no phase transformations were observed. Like Ta 2 Al C , but unlike many related phases such as Ti 4 Al N 3 , Ti 3 Si C 2 , Ti 3 Ge C 2 , and Zr 2 In C , the compressibility of Ta 4 Al C 3 along the c and a axes are almost identical. The bulk modulus of Ta 4 Al C 3 , 261 ± 2 GPa , is ≈ 4 % greater than that of Ta 2 Al C . Both, however, are ≈ 37 % lower than the 345 ± 9 GPa of TaC.

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Collaboration types
Domestic collaboration
Web of Science research areas
Physics, Applied
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