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Impact of CrIS-Derived NH 3 Emission Updates on Simulated Nitrate and Ammonium Aerosols over East Asia
Journal article   Peer reviewed

Impact of CrIS-Derived NH 3 Emission Updates on Simulated Nitrate and Ammonium Aerosols over East Asia

Kyoung-Min Kim, Si-Wan Kim, Seunghwan Seo, Congmeng Lyu, Brian C McDonald, Mark W Shephard, Jose L Jimenez, Hwajin Kim, Cheolsoo Lim, Hye-Jung Shin, …
Environmental science & technology
24 Dec 2025
PMID: 41445096
url
https://doi.org/10.1021/acs.est.5c08113View
Published, Version of Record (VoR) Open

Abstract

secondary inorganic aerosols NH3 ammonium CrIS nitrate WRF-Chem
Fine particulate matter (PM diameter <1 μm) strongly affects air quality and health, with sulfate, nitrate, and ammonium (SNA) as major components across East Asia. Because NH is a key precursor of SNA formation, accurate NH emission data are essential for reliable SNA simulations. This study improves NH emission inventories in East Asia by integrating the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) and the Cross-Track Infrared Sounder (CrIS), with extensive evaluation against ground-based and aircraft observations from the Korea-United States Air Quality (KORUS-AQ) campaign. Iterative linear inversion of NH emissions using WRF-Chem markedly enhances simulations of nitrate and ammonium, in agreement with both the aircraft and surface measurements. The absolute biases of nitrate and ammonium were reduced from 89.7 and 50.1% to 13.6 and 0.6%, respectively, compared to the aircraft observations over Seoul. However, uncertainties in nocturnal NH emissions remain potential sources of nighttime biases in nitrate and ammonium. Overall, the results indicate that nitrate aerosol in most of East Asia is sensitive to NH emission changes. To advance our understanding of SNA formation and support effective aerosol mitigation policies, improved characterization of the diurnal cycle of NH emissions through ground-based monitoring and high-resolution geostationary satellite observations is urgently needed.

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Collaboration types
Domestic collaboration
International collaboration
Web of Science research areas
Engineering, Environmental
Environmental Sciences
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