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Isothermal Oxidation of Ti2SC in Air
Journal article

Isothermal Oxidation of Ti2SC in Air

Shahram Amini, Andrew R. McGhie and Michel W. Barsoum
Journal of the Electrochemical Society, v 156(7), pp P101-P106
01 Jan 2009
DOI: https://doi.org/10.1149/1.3117348

Abstract

Electrochemistry Materials Science Materials Science, Coatings & Films Physical Sciences Science & Technology Technology
The oxidation behavior of fully dense Ti2SC was studied thermogravimetrically in air in the 500-800 degrees C temperature range. The oxidation product was a single-layer of rutile in all cases. At 800 degrees C, the oxide layer was not protective and the oxidation kinetics were rapid. At 600 and 700 degrees C, and up to similar to 50 h, the kinetics were parabolic before they became linear. It was only at 500 degrees C that the weight gain reached a plateau after a 50 h initial parabolic regime. Mass spectrometry of the gases evolved during oxidation confirmed that both CO2 and SO2 are oxidation products. The overall oxidation reaction is thus Ti2SC + 4O(2) -> 2TiO(2) + SO2 + CO2. On the basis of this and previous work, we conclude that oxidation occurs by the outward diffusion of titanium, sulfur, and carbon, the latter two either as atoms or in the form of CO2 and SO2 and, most probably, the inward diffusion of oxygen. Mesopores and microcracks were found in all rutile layers formed except those formed at 500 degrees C. The presence of these defects is believed to have led to significantly higher oxidation rates as compared to other rutile-forming ternary carbides, such as Ti3SiC2. (C) 2009 The Electrochemical Society. [DOI: 10.1149/1.3117348] All rights reserved.

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Electrochemistry
Materials Science, Coatings & Films
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