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Isotope Ratios of H, C, and O in CO2 and H2O of the Martian Atmosphere
Journal article   Open access   Peer reviewed

Isotope Ratios of H, C, and O in CO2 and H2O of the Martian Atmosphere

Chris R. Webster, Paul R. Mahaffy, Gregory J. Flesch, Paul B. Niles, John H. Jones, Laurie A. Leshin, Sushil K. Atreya, Jennifer C. Stern, Lance E. Christensen, Tobias Owen, …
Science (American Association for the Advancement of Science), v 341(6143), pp 260-263
19 Jul 2013
PMID: 23869013
url
https://resolver.caltech.edu/CaltechAUTHORS:20200505-091430499View
Accepted (AM)Open Access (License Unspecified) Open

Abstract

Multidisciplinary Sciences Science & Technology Science & Technology - Other Topics
Stable isotope ratios of H, C, and O are powerful indicators of a wide variety of planetary geophysical processes, and for Mars they reveal the record of loss of its atmosphere and subsequent interactions with its surface such as carbonate formation. We report in situ measurements of the isotopic ratios of D/H and O-18/O-16 in water and C-13/C-12, O-18/O-16, O-17/O-16, and (CO)-C-13-O-18/(CO)-C-12-O-16 in carbon dioxide, made in the martian atmosphere at Gale Crater from the Curiosity rover using the Sample Analysis at Mars (SAM)'s tunable laser spectrometer (TLS). Comparison between our measurements in the modern atmosphere and those of martian meteorites such as ALH 84001 implies that the martian reservoirs of CO2 and H2O were largely established similar to 4 billion years ago, but that atmospheric loss or surface interaction may be still ongoing.

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Domestic collaboration
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Geochemistry & Geophysics
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