Journal article
Kinetic and Thermodynamic Considerations Regarding Interphase Formation in Thermosetting Composite Systems
The Journal of adhesion, v 44(1-2)
01 Jan 1994
Abstract
Thermodynamic and kinetic treatments are employed to analyze the role of preferential adsorption and diffusion in the formation of interphase regions in thermosetting composities. The thermodynamic analyses show that a driving force exists for the preferential adsorption of amines onto carbon fiber surfaces in amine-epoxy systems. Scaling analyses, based on kinetic considerations, lead to the identification of reaction-diffusion time regimes that control interphase formation in sized and unsized fiber systems. These considerations provide guidelines for the selection of material formulations and processing conditions that may be used to tailor behavior of the interphase region in thermosetting composites.
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Details
- Title
- Kinetic and Thermodynamic Considerations Regarding Interphase Formation in Thermosetting Composite Systems
- Creators
- G. R. Palmese - University of DelawareR. L. McCullough - Center for Composite Materials and Department of Chemical Engineering , University of Delaware
- Publication Details
- The Journal of adhesion, v 44(1-2)
- Publisher
- Taylor & Francis Group
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- Chemical and Biological Engineering
- Web of Science ID
- WOS:A1994QH68700003
- Scopus ID
- 2-s2.0-84954696597
- Other Identifier
- 991019201376004721
InCites Highlights
Data related to this publication, from InCites Benchmarking & Analytics tool:
- Web of Science research areas
- Engineering, Chemical
- Materials Science, Multidisciplinary
- Mechanics