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LeChatelier dynamics
Journal article   Peer reviewed

LeChatelier dynamics

Robert Gilmore
Molecular physics, v 106(8), pp 991-997
20 Apr 2008

Abstract

dynamics LeChatelier's Principle statics
Dynamics of the relaxation of a perturbed thermodynamic system to equilibrium is determined by the generalised eigenvalue equation . Here S αβ is a matrix of linear response coefficients and is a matrix of kinetic coefficients. We describe LeChatelier's Principle and both its static and dynamical symmetries, and treat cases in which there are multiple relaxation channels. The treatment simplifies when the relaxation channels have widely separated time scales. † Note: This paper is part of the Levine special issue published in Volume 106 (2-4) of the journal.

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Web of Science research areas
Chemistry, Physical
Physics, Atomic, Molecular & Chemical
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