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LiV2O5 nanobelts for high capacity lithium-ion battery cathodes
Journal article   Open access   Peer reviewed

LiV2O5 nanobelts for high capacity lithium-ion battery cathodes

Dmitrii A. Semenenko, Daniil M. Itkis, Ekaterina A. Pomerantseva, Eugene A. Goodilin, Tatiana L. Kulova, Alexander M. Skundin and Yurii D. Tretyakov
Electrochemistry communications, v 12(9), pp 1154-1157
01 Sep 2010
url
https://doaj.org/article/6159698563cd40928be4f5de8efdfc03View
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Abstract

Electrochemistry Physical Sciences Science & Technology
5-10 mu m long, typically 200-300 nm wide, and several nanometers thick LixV2O5 (x similar to 0.8) nanobelts with the delta-type crystal structure were synthesized by a hydrothermal treatment of Li+-exchanged V2O5 gel. When dried at 200 degrees C under vacuum prior to electrochemical testing, the as-prepared nanobelts underwent the well-known delta ->epsilon ->gamma-phase transition giving a mixture of epsilon and gamma phases as a nanocomposite electrode material. Such a simple preparation procedure guarantees a yield of material with drastically enhanced initial discharge specific capacity of 490 rnAh/g and great cyclability. The enhanced electrochemical performance is attributed to the complex of experimental procedures including post-synthesis treatment of the single-crystalline LixV2O5 nanobelts. (C) 2010 Elsevier B.V. All rights reserved.

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Electrochemistry
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