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Mesoporous MXene powders synthesized by acid induced crumpling and their use as Na-ion battery anodes
Journal article   Open access

Mesoporous MXene powders synthesized by acid induced crumpling and their use as Na-ion battery anodes

Varun Natu, Mallory Clites, Ekaterina Pomerantseva and Michel W. Barsoum
Materials research letters, v 6(4), pp 230-235
03 Apr 2018
url
https://doi.org/10.1080/21663831.2018.1434249View
Published, Version of Record (VoR)CC BY-NC V4.0 Open

Abstract

3D mesoporous architecture acid-induced crashing crumpled nanosheets MXenes sodium-ion battery
Manipulating the shapes of, otherwise flat, two-dimensional, 2D, flakes is important in many applications. Herein by simply decreasing the pH of a Ti 3 C 2 T x MXene colloidal suspension, the 2D nanolayers crash out into crumpled flakes, resulting in randomly oriented powders, with a mesoporous architecture. Electrodes made with the latter showed capacities of 250 mAh g −1 at 20 mA g −1 in sodium-ion batteries. The rate performance, 120 mAh g −1 at 500 mA g −1 , was also respectable. This acid-induced, reversible, crumpling approach is facile and scalable and could prove important in electrochemical, biological, catalytic, and environmental MXene-based applications. By simply decreasing the pH of a Ti 3 C 2 T x colloidal suspension, we induce the 2D flakes flocculate into mesoporous crumpled flakes, that we then show can be used as Na-ion battery anodes.

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Web of Science research areas
Materials Science, Multidisciplinary
Metallurgy & Metallurgical Engineering
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