Published, Version of Record (VoR)CC BY-NC V4.0, Open
Abstract
3D mesoporous architecture acid-induced crashing crumpled nanosheets MXenes sodium-ion battery
Manipulating the shapes of, otherwise flat, two-dimensional, 2D, flakes is important in many applications. Herein by simply decreasing the pH of a Ti
3
C
2
T
x
MXene colloidal suspension, the 2D nanolayers crash out into crumpled flakes, resulting in randomly oriented powders, with a mesoporous architecture. Electrodes made with the latter showed capacities of 250 mAh g
−1
at 20 mA g
−1
in sodium-ion batteries. The rate performance, 120 mAh g
−1
at 500 mA g
−1
, was also respectable. This acid-induced, reversible, crumpling approach is facile and scalable and could prove important in electrochemical, biological, catalytic, and environmental MXene-based applications.
By simply decreasing the pH of a Ti
3
C
2
T
x
colloidal suspension, we induce the 2D flakes flocculate into mesoporous crumpled flakes, that we then show can be used as Na-ion battery anodes.
Mesoporous MXene powders synthesized by acid induced crumpling and their use as Na-ion battery anodes
Creators
Varun Natu - Drexel University
Mallory Clites - Drexel University
Ekaterina Pomerantseva - Drexel University
Michel W. Barsoum - Drexel University
Publication Details
Materials research letters, v 6(4), pp 230-235
Publisher
Taylor & Francis
Grant note
1609272 / Division of Materials Research (10.13039/100000078)
National Science Foundation (10.13039/501100008982)
621-2012-4430 / Swedish Research Council (10.13039/501100004359)
Resource Type
Journal article
Language
English
Academic Unit
Materials Science and Engineering
Web of Science ID
WOS:000432339300002
Scopus ID
2-s2.0-85042476812
Other Identifier
991019169631204721
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