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Metal Organic Framework Micro/Nanopillars of Cu(BTC)center dot 3H(2)O and Zn(ADC)center dot DMSO
Journal article   Open access   Peer reviewed

Metal Organic Framework Micro/Nanopillars of Cu(BTC)center dot 3H(2)O and Zn(ADC)center dot DMSO

Arben Kojtari and Hai-Feng Ji
Nanomaterials (Basel, Switzerland), v 5(2), pp 565-576
01 Jun 2015
PMID: 28347026
url
https://www.mdpi.com/2079-4991/5/2/565/pdfView
Published, Version of Record (VoR) Open
url
https://doi.org/10.3390/nano5020565View
Published, Version of Record (VoR) Open

Abstract

Chemistry Chemistry, Multidisciplinary Materials Science Materials Science, Multidisciplinary Nanoscience & Nanotechnology Physical Sciences Physics Physics, Applied Science & Technology Science & Technology - Other Topics Technology
In this work, we report the optical and thermal properties of Cu(BTC)center dot 3H(2)O (BTC = 1,3,5-benzenetricarboxylic acid) and Zn(ADC)center dot DMSO (ADC = 9,10-anthracenedicarboxylic acid, DMSO = dimethyl sulfoxide) metal-organic frameworks (MOFs) micro/nanopillars. The morphologies of MOFs on surfaces are most in the form of micro/nanopillars that were vertically oriented on the surface. The size and morphology of the pillars depend on the evaporation time, concentration, solvent, substrate, and starting volume of solutions. The crystal structures of the nanopillars and micropillars are the same, confirmed by powder XRD. Zn(ADC)center dot DMSO pillars have a strong blue fluorescence. Most of ADC in the pillars are in the form of monomers, which is different from ADC in the solid powder.

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Web of Science research areas
Chemistry, Multidisciplinary
Materials Science, Multidisciplinary
Nanoscience & Nanotechnology
Physics, Applied
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