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Metal ion-assisted self-assembly of complexes for controlled and sustained release of minocycline for biomedical applications
Journal article   Open access   Peer reviewed

Metal ion-assisted self-assembly of complexes for controlled and sustained release of minocycline for biomedical applications

Zhiling Zhang, Zhicheng Wang, Jia Nong, Camilla A Nix, Hai-Feng Ji and Yinghui Zhong
Biofabrication, v 7(1), pp 015006-015006
20 Jan 2015
PMID: 25599696
url
https://doi.org/10.1088/1758-5090/7/1/015006View
Published, Version of Record (VoR) Open

Abstract

controlled release drug delivery metal ion minocycline complex
This study reports the development of novel drug delivery complexes self-assembled by divalent metal ion-assisted coacervation for controlled and sustained release of a hydrophilic small drug molecule minocycline hydrochloride (MH). MH is a multifaceted agent that has demonstrated therapeutic effects in infection, inflammation, tumor, as well as cardiovascular, renal, and neurological disorders due to its anti-microbial, anti-inflammatory, and cytoprotective properties. However, the inability to translate the high doses used in experimental animals to tolerable doses in human patients limits its clinical application. Localized delivery can potentially expose the diseased tissue to high concentrations of MH that systemic delivery cannot achieve, while minimizing the side effects from systemic exposure. The strong metal ion binding-assisted interaction enabled high drug entrapment and loading efficiency, and stable long term release for more than 71 d. Released MH demonstrated potent anti-biofilm, anti-inflammatory, and neuroprotective activities. Furthermore, MH release from the complexes is pH-sensitive as the chelation between minocycline and metal ions decreases with pH, allowing 'smart' drug release in response to the severity of pathology-induced tissue acidosis. This novel metal ion binding-mediated drug delivery mechanism can potentially be applied to other drugs that have high binding affinity for metal ions and may lead to the development of new delivery systems for a variety of drugs.

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33 citations in Scopus

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Web of Science research areas
Engineering, Biomedical
Materials Science, Biomaterials
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