Journal article
Microbiological and chemical methods in the asymmetric oxidation of sulfides: A comparative study for the preparation of ( S)-vinyl sulfoxides
Tetrahedron: asymmetry, v 3(5), pp 629-636
1992
Featured in Collection : UN Sustainable Development Goals @ Drexel
Abstract
The enantiogenicity of biological and chemical oxidation at the sulfur atom was studied on a series of prochiral vinyl sulfides for the preparation of sulfoxides of (
S)-absolute configuration. Using either fungal cultures, Sharpless-modified reagent or chiral oxaziridine, the enantiomeric excesses varied according to the substrate's steric and/or electronic structure; the three methods were complementary.
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Details
- Title
- Microbiological and chemical methods in the asymmetric oxidation of sulfides: A comparative study for the preparation of ( S)-vinyl sulfoxides
- Creators
- Claude Rossi - Institut PascalAnnie Fauve - Institut PascalMichel Madesclaire - Groupe de Pharmacochimie, UFR de Pharmacie, B.P. 38, 63001 Clermont-Ferrand - FranceDanielle Roche - Groupe de Pharmacochimie, UFR de Pharmacie, B.P. 38, 63001 Clermont-Ferrand - FranceFranklin A. Davis - Drexel UniversityR. Thimma Reddy - Drexel University
- Publication Details
- Tetrahedron: asymmetry, v 3(5), pp 629-636
- Publisher
- Elsevier
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- [Retired Faculty]
- Web of Science ID
- WOS:A1992HU18700012
- Scopus ID
- 2-s2.0-0026638286
- Other Identifier
- 991019173848604721
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- Collaboration types
- Domestic collaboration
- International collaboration
- Web of Science research areas
- Chemistry, Inorganic & Nuclear
- Chemistry, Organic
- Chemistry, Physical