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Moisture sorption, transport, and hydrolytic degradation in polylactide
Journal article   Peer reviewed

Moisture sorption, transport, and hydrolytic degradation in polylactide

Richard A Cairncross, Jeffrey G Becker, Shri Ramaswamy and Ryan O'Connor
Applied biochemistry and biotechnology, v 131(1-3), p774
Mar 2006
PMID: 18563653

Abstract

Biodegradation, Environmental Hydrolysis Biopolymers - chemistry Polyesters - chemistry Absorption Specimen Handling - methods Water - analysis Materials Testing Diffusion Crystallization - methods
Management of moisture penetration and hydrolytic degradation of polylactide (PLA) is extremely important during the manufacturing, shipping, storage, and end-use of PLA products. Moisture transport, crystallization, and degradation, in PLA have been measured through a variety of experimental techniques including size-exclusion chromatography, differential scanning calorimetry, and X-ray diffraction. Quartz crystal microbalance and dynamic vapor sorption experiments have also been used to measure moisture sorption isotherms in PLA films with varying crystallinity. A surprising result is that, within the accuracy of the experiments, crystalline and amorphous PLA films exhibit identical sorption isotherms.

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Collaboration types
Domestic collaboration
Web of Science research areas
Biochemistry & Molecular Biology
Biotechnology & Applied Microbiology
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